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钙钛矿氧化物中的结构:性质关联(英文版)

钙钛矿氧化物中的结构:性质关联(英文版)

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作 者: 高然 著
出版社: 湖南大学出版社
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标 签: 暂缺

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ISBN: 9787566719331 出版时间: 2020-06-01 包装: 平装
开本: 16开 页数: 169 字数:  

内容简介

  《钙钛矿氧化物中的结构-性质关联(英文版)》主要包括钙钛矿氧化物薄膜的外延生长、钙钛矿氧化物薄膜晶体结构的调控手段以及表征手段、薄膜物理/化学性质的测量表征方法等内容。《钙钛矿氧化物中的结构-性质关联(英文版)》讨论了对于外延钙钛矿功能型氧化物薄膜晶体结构的精确调控,以及其相对应的物理/化学特性随结构调控的演变;并以四种不同物理特性的代表性钙钛矿氧化物为例,系统性地讨论了先进的材料外延生长。表征以及调控手段;创新地提出了一系列物化性质表征测试方法;深入地阐释了钙钛矿氧化物材料的结构-性质内在关联。《钙钛矿氧化物中的结构-性质关联(英文版)》可作为高等院校相关专业学生的参考用书,也可供企业人士参考使用。

作者简介

  高然,男,现任职于阿里巴巴达摩院,美国加利福尼亚大学伯克利分校材料科学与工程系博士毕业,2015-2019年,师从美国功能氧化物薄膜专家Lane W.Martin 教授,专攻氧化物外延薄膜的生长、结构调控、以及薄膜性能研究,其研究论文发表于世界材料科学期刊如Nature Materials,Advanced Materials, Nature Communication,Chemistry of Materials 等,发表SCI一区论文20余篇。他多次参与美国材料科学协会与美国物理协会会议并发表演讲。

图书目录

List of Figures
List of Tables
List of Symbols and Abbreviations
1 Structure-property coupling in perovskite oxides
1.1 Introduction to perovskite oxides
1.2 Lattice degree of freedom and structural features
1.3 Motivation and opportunities
1.4 Statement and organization of the dissertation
2 The control and manipulation of perovskite structures
2.1 An epitaxial thin-film approach
2.2 Control of lattice structures in perovskite thin films
2.3 Control of surface structures in perovskite thin films
3 Characterization of perovskite heterostructures
3.1 Structural characterization of perovskite oxides
3.2 Physical properties and characterization
4 Structure control,magnetism,and transport in SrRuO
4.1 Introduction
4.2 Sample design and thin-film synthesis
4.3 Structural characterization
4.4 Octahedra rotational domains
4.5 Impact on physical properties of SrRuOs
4.6 Conclusions
5 Control of antiferro-/ferroelectricity in PbZrO3
5.1 Introduction
5.2 PbZrO,thin-film growth dynamics
5.3 Structural and chemistry characterization
5.4 Electrical characterization
5.5 Lattice symmetry determination
5.6 Energy ground states in lead-excess PbZrOs
5.7 Conclusions
6 Designing optimal ion-conducting perovskite structure
6.1 Introduction
6.2 Strain engineering and quantification of structural features
6.3 Ion-transport measurement
6.4 First-principle calculations
6.5 Experimental realization of the optimal structure
6.6 Conductivity measurement in superlatice structures
6.7 Conclusions
7 Correlating surface orientations and electrochemistry
7.1 Introduction
7.2 Epitaxial all-perovskite,half-cell structures
7.3 Heterostructure synthesis and characterization of the half-cels
7.4 The fabrication of the epitaxial half cells
7.5 Validating the epitaxial half cells
7.6 Orientation-dependent gas-exchange kinetics
7.7 Rate-limiting step in the gas exchange reactions
7.8 Conclusions and future works
8 Summary of findings and suggestions
8.1 Summary of findings
8.2 Suggestions for future work
References
Appendix A Pseudo-cubic lattice notation
Appendix B Characterization of thin-film chemistry
B.1 Rutherford backscattering spectrometry
B.2 X-ray photoelectron spectroscopy
B.3 Low-energy ion scattering spectroscopy
Appendix C Electrochemical impedance spectroscopy
C.1 Ionic diffusion in mixed conductors
C.2 Surface reaction at solid-gas interface
Acknowledgments

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